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 Characterization studies in microporous silica membranes. Membrane characterization through 129Xe NMR, gas transport, and gas adsorption experiments
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Characterization studies in microporous silica membranes. Membrane characterization through 129Xe NMR, gas transport, and gas adsorption experiments

автор Lawrence M. издательство Книга по Требованию Физическая химия
Cтраниц 260        мягкая обложка       
Аннотация:Thermal treatment is found to have almost no effect on void space, while profoundly affecting transport rates. We make the important distinction between traditional characterization techniques, which characterize void space, and size exclusion experiments that probe the small subset of features that actually control diffusion. We attribute the transport changes to the removal of water from the system, which increases pore interconnectivity thereby allowing alternate diffusion pathways. In this study we seek to develop techniques to characterize these features, and to study the effects of thermal treatment on the properties of microporous silica membranes. The results of size exclusion, gas adsorption, 129Xe NMR, and transport experiments are combined to propose a model of the amorphous microporous silica structure. Current efforts to design more efficient gas separation membranes are hampered by an incomplete understanding of material structure and of the microscopic features that control gas diffusion in membranes.
Автор: Lawrence M.
Издательство: Книга по Требованию
Год:2009
Цена:
3190 руб
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Поиск: Characterization studies in microporous silica membranes. Membrane characterization through 129Xe NMR, gas transport, and gas adsorption experiments
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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