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 Intramolecular Reactions of Diazo Compounds in Natural Product Synthesis Intramolecular Cyclopropanation/Thermal Fragmentation strategy.
Наименование:

Intramolecular Reactions of Diazo Compounds in Natural Product Synthesis Intramolecular Cyclopropanation/Thermal Fragmentation strategy.

автор Florence M. издательство Книга по Требованию Физическая химия
Cтраниц 80        мягкая обложка       
Аннотация:The substrate is subjected to the transition metal- catalyzed diazo decomposition conditions to afford the desired intramolecular cyclopropanation product. These structures are accessed starting with the preparation of functionalized cyclobutenes and applying a new intramolecular cyclopropanation/thermal fragmentation strategy. The development of a novel methodology toward the construction of 5-7 ring systems. These ring systems are skeletons of a versatile class of many natural products with diverse biological activities. The added functionality provides a handle for further manipulations for the synthesis of natural products with more structural complexity. To expand the scope of these reactions to include additional functionality, a tethered diazo moiety has been attached onto the cyclobutene.
Автор: Florence M.
Издательство: Книга по Требованию
Год:2009
Цена:
1996 руб
Нет в наличии
Поиск: Intramolecular Reactions of Diazo Compounds in Natural Product Synthesis Intramolecular Cyclopropanation/Thermal Fragmentation strategy.
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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