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 Asymmetric Baeyer-Villiger Oxidations Using Biocatalysts. Development and Application of 2nd Generation of Biocatalysts
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Asymmetric Baeyer-Villiger Oxidations Using Biocatalysts. Development and Application of 2nd Generation of Biocatalysts

автор Radka S. издательство Книга по Требованию Экономическая теория
Cтраниц 288        мягкая обложка       
Аннотация:For the transformation of achiral ketones to chiral lactones, Baeyer-Villiger monooxygenases (BVMOs) were utilized, since these enzymes exhibit wide substrate specificity and high enantioselectivity. As a direct consequence of this research, a metabolically independent biocatalyst was developed, which performs cofactor regeneration concomitantly with the oxygenation reaction. . Such a system is very attractive for industrial applications as operational costs are dramatically reduced due to the absence for the requirement of co-factor recycling. Chiral lactones are important building blocks in organic synthesis. A broad range of useful products are accessible via enantioselective Baeyer-Villiger oxidation of simple ketones. Various cofactor recycling options have also been considered during this study. The advantage of this approach is that BVMOs can generate several chiral centers in a single biotransformation step. Such lactones can serve as versatile building blocks in natural product and bioactive compound synthesis.
Автор: Radka S.
Издательство: Книга по Требованию
Год:2009
Цена:
3214 руб
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Поиск: Asymmetric Baeyer-Villiger Oxidations Using Biocatalysts. Development and Application of 2nd Generation of Biocatalysts
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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