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 Designing Models to Elucidate Radical Reaction Mechanisms. Model Studies of Diol-dehydratase-catalyzed Reactions and Excess Electron Transfer
Наименование:

Designing Models to Elucidate Radical Reaction Mechanisms. Model Studies of Diol-dehydratase-catalyzed Reactions and Excess Electron Transfer

издательство Книга по Требованию Физическая химия
Cтраниц 188        мягкая обложка       
Аннотация:Both the radical-generating and the radical-detecting processes must be fast enough to allow accurate kinetic measurements. The designing process was illustrated during the studies of DD-catalyzed reactions and EET. This model-designing strategy was applied to mimic the radical reactions catalyzed by diol dehydratase (DD) and the excess electron transfer (EET, or reductive electron transfer) process, where radical anions are the intermediates, in biological molecules. The molecule must incorporate a radical-generating element that can give the target radical under certain condition, such as heat or light (e. g. , laser), and a radical-detecting element that can detect the product radical once the reaction occurs. This book talks about how to design a model organic molecule to study radical reaction mechanisms.
Издательство: Книга по Требованию
Год:2008
Цена:
2768 руб
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Поиск: Designing Models to Elucidate Radical Reaction Mechanisms. Model Studies of Diol-dehydratase-catalyzed Reactions and Excess Electron Transfer
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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Спецификация каркаса информационной системы с распределенной...

Пакет co roller содержит классы, работающие с моделью данных приложения. Пакет model.fac представляет структуры фактов, которыми обменивается клиентское приложение с сервером приложений. Пакет model.me a представляет структуры описывающих факты, т.е. метамодель, которыми обменивается клиентское приложение с сервером приложений. Пакет model.securi y представляет структуры, описывающие безопасность доступа к фактам и метамодели, которыми также обменивается клиентское приложение с сервером приложений. Пакеты source.fac , source.me a и source.securi y отвечают за взаимодействие между клиентским приложением и сервером приложений и поддерживают между ними обмен фактами (model.fac ), метаданными (model.me a) и безопасностью (model.securi y) не зависимо от используемой разработчиком распределенной технологии. Другими словами, на основе них следует делать стабы (s ub) . Сервер приложений состоит из 9 пакетов. Пакеты model.fac , model.me a, model.securi y такие же, как на стороне клиентского приложения. Они служат value-объектами обмена информацией между сервером приложений и клиентским приложением. Пакеты source.fac , source.me a и source.securi y на стороне сервера отвечают за взаимодействие между клиентским приложением и сервером приложений.
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