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 The Chemical and Physical Properties of Polychalcogens. Dialkoxydisulfides, Thionosulfites and Polysulfides
Наименование:

The Chemical and Physical Properties of Polychalcogens. Dialkoxydisulfides, Thionosulfites and Polysulfides

автор Eli Z. издательство Книга по Требованию Физическая химия
Cтраниц 500        мягкая обложка       
Аннотация:Complimentary to this thermal process, the decomposition of dialkoxy disulfides was also investigated. Theoretical modeling on the relative ground state energies of dialkoxy disulfides is also described. The kinetics of desulfurization of acyclic aromatic tri- and tetrasulfides is described. The origin of the high rotational barrier was also verified experimentally. The optimized synthesis of acyclic dialkoxy disulfides and aromatic polysulfides is described and their physical properties probed. These modeling studies were successfully corroborated experimentally. It has been ascertained that the equilibrium position between the two isomers can be influenced by the ring size of the molecule; larger rings promote the dialkoxy disulfide isomer. In particular, the origin of the high barrier to rotation in the dialkoxy disulfides was determined to be due to a generalized anomeric effect. Tetrasulfides were found to transfer a sulfur atom to triphenylphosphine over ten times faster than their trisulfide analogues.
Автор: Eli Z.
Издательство: Книга по Требованию
Год:2009
Цена:
3233 руб
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Поиск: The Chemical and Physical Properties of Polychalcogens. Dialkoxydisulfides, Thionosulfites and Polysulfides
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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