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 Oxidative Dehydrogenation of Ethane to Ethylene with H2S and Sulfur. Reaction, Mechanism and the Process
Наименование:

Oxidative Dehydrogenation of Ethane to Ethylene with H2S and Sulfur. Reaction, Mechanism and the Process

автор Sunlan L. издательство Книга по Требованию Другие общетехнические дисциплины
Cтраниц 180        мягкая обложка       
Аннотация:The steam cracking process currently used for ethylene production is highly endothermic and relies on methane combustion to satisfy its large energy demand. The cost of burning methane and the related CO2 emission has been a concern for the operations. Consequently, oxidative dehydrogenation (ODH) of ethane, an exothermic or mild endothermic reaction using oxidizing agent, has been widely investigated as an alternative to steam cracking. This research presents interesting possibility of producing ethylene at a lower energy cost by using sulfur and the waste heat from the Claus process, and should be especially useful for professionals working on olefin production, oxidative dehydrogenation or oxidative coupling of hydrocarbons. This book investigated the chemistry of ODH of ethane to ethylene with sulfur as oxidant, demonstrating that sulfur species generated either from liquid sulfur or formed in-situ by H2S/O2 reaction were able to selectively convert ethane to ethylene. Specifically, a single pass ethylene yield of 76% with the selectivity of 89% was obtained in the ethane - sulfur reaction at conditions comparable to steam cracking.
Автор: Sunlan L.
Издательство: Книга по Требованию
Год:2009
Цена:
2783 руб
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Поиск: Oxidative Dehydrogenation of Ethane to Ethylene with H2S and Sulfur. Reaction, Mechanism and the Process
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
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Водные ресурсы

Так, например, при окислении весьма распространенного в породах пирита получается сернокислое железо: FeS2 4O2 ? Fe2 2SO42-, а при действии угольной кислоты – карбонат железа: FeS2 2Н2СОз ? Fe2 2НСОз H2S S. Соединения кремния в природных водах могут быть в виде кремниевой кислоты. При рН ?8 кремниевая кислота находится практически в недиссоциированном виде; при рН ?8 кремниевая кислота присутствует совместно с HSiO3, а при рН >П - только HSiOз. Часть кремния находится в коллоидном состоянии, с частицами состава HSiO2 H2O, а также в виде поликремневой кислоты: X SiO2 ? H2O. В природных водах присутствуют также Аl3 , Mg2 и другие катионы. Помимо веществ ионного типа природные воды содержат также газы и органические и грубодисперсные взвеси. Наиболее распространенными в природных водах газами являются кислород и углекислый газ. Источником кислорода является атмосфера, углекислоты - биохимические процессы, происходящие в глубинных слоях земной коры, углекислота из атмосферы. Из органических веществ, попадающих извне, следует отметить гуминовые вещества, вымываемые водой из гумусовых почв (торфяников, сапропелитов и др.). Большая часть из них находится в коллоидном состоянии.
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