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 Cascade Reaction It allows the organic synthesis of complex multinuclear molecules from a single acyclic precursor. Often a functional group is generated in situ from
Наименование:

Cascade Reaction

автор Frederic P. издательство Книга по Требованию Физическая химия
Cтраниц 108        мягкая обложка       
Аннотация:It allows the organic synthesis of complex multinuclear molecules from a single acyclic precursor. Often a functional group is generated in situ from the previous chemical transformation. The substrate contains many functional groups that take part in chemical transformations one at the time. A cascade reaction or tandem reaction or domino reaction is a consecutive series of intramolecular organic reactions which often proceed via highly reactive intermediates. In cascade reactions one can identify an initiation site, a relay moiety and a termination moiety. In this sense it differs from the definition of a biochemical cascade. The definition includes the prerequisite intramolecular in order to distinguish this reaction type from a multi-component reaction. A cascade reaction is sometimes called a living reaction because it shares some characteristics with a living polymerization. The main advantages of a cascade reaction in organic synthesis are that the reaction is often fast due to its intramolecular nature, the reaction is also clean, displays high atom economy and does not involve workup and isolation of many intermediates.
Автор: Frederic P.
Издательство: Книга по Требованию
Год:2010
Цена:
1598 руб
Нет в наличии
Поиск: Cascade Reaction
НОВЫЙ ГОД СИМВОЛ 2013 ГОДАУКРАШЕНИЯ
КАРНАВАЛ НА НОВЫЙ ГОД РАСПРОДАЖА
Ортомолекулярная медицина Orthomol Устрание причин заболеваний. Ортомоль это новый метод для лечения и профилактики болезней. Orthomol - ортомолекулярная медицина.
Иностранные заимствования в лексике английского...

Например, barouche (итальянское слово baroccio — барокко); cohl-rabi (ит. cavoli rape — кольраби) заимствованы из немецкого языка. Большинство итальянских слов до XVI века было заимствовано через французский, и только с XVI века появляются заимствования непосредственно из итальянского языка. Самые ранние (XIV-XV вв.) заимствования относятся к торговле и военному делу. Так из области торговли и финансов были заимствованы слова: duca , millio , lombard. Из области военного дела и мореплавания: alarm (тревога), briga d (бандит), bark (барка). В XVI веке экономические связи с Италией вызвали новые заимствования: cara (карат), raffic (движение транспорта), porcelai (фарфор), co raba d (контрабанда), ba krup (банкрот), soldo (сольдо), ba alio , squadro , ci adel, pis ol. Однако наибольшее количество слов, заимствованных из итальянского языка, связано с областью искусства (литература, живопись, музыка, архитектура). Например: so e , s a za, mo o, model, mi ia ure, mado a, fresco. Другие заимствования этого периода: ba di , bire a, mus achio, lo ery, bravo, duel, cavalcade, escor , ar ichoke, go dola. В XVII веке возрастает количество заимствований, относящихся к общественной жизни, торговле, а также искусству и музыке, например: ma ifes o, i rigue, bulle i , risk, umbrella, balco y, corridor, pedal, solo, opera, vivace, pia o, largo, allegro, gro o, volca o, cascade.
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